Const ADS_PROPERTY_CLEAR = 1
Const ADS_PROPERTY_UPDATE = 2
Const ADS_PROPERTY_APPEND = 3
Const ADS_PROPERTY_DELETE = 4

‘Using PutEx to append addition values to multi-value attribute.
arrayValues(0) = CStr(3)
arrayValues(1) = CStr(4)
myObject.PutEx ADS_PROPERTY_APPEND, “myAttrib”, arrayValues

from: http://support.microsoft.com/kb/260251

So

objContainer.PutEx ADS_PROPERTY_APPEND, “member”, “CN=” & strUsername & “,” & strUserOU & “,” & strRootDSE   
objContainer.SetInfo

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